Low-energy selective capture of carbon dioxide by a pre-designed elastic single-molecule trap.
نویسندگان
چکیده
Single-molecule trap: Easy activation of the water-stable metal-organic framework PCN-200 provides a new route to low-energy selective CO(2) capture through stimuli-responsive adsorption behavior. This elastic CO(2) trapping effect was confirmed by single-component and binary gas-adsorption isotherms and crystallographic determination.
منابع مشابه
Unprecedented activation and CO2 capture properties of an elastic single-molecule trap.
The activation and CO2 capture properties of a microporous metal-organic framework with elastic single-molecule traps were systematically investigated. This material shows a unique low-energy gas-purge activation capability, high CO2 adsorption selectivities over various gases and optimized working capacities per energy of 2.9 mmol kJ(-1) at 128 °C.
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عنوان ژورنال:
- Angewandte Chemie
دوره 51 39 شماره
صفحات -
تاریخ انتشار 2012